Chemical bonding - Hypervalence, Electrons, Atoms

chemical bonding

Table of Contents

Introduction
Historical review
- Emergence of quantitative chemistry
  - The law of conservation of mass
  - The law of definite proportions
  - The law of multiple proportions
  - Dalton’s atomic theory
- Features of bonding
  - Valence
  - Ionic and covalent compounds
- The periodic table
- Additional evidence of atoms
  - Avogadro’s law
  - Kinetic theory of gases
  - Visual images of atoms
- Molecular structure
- Internal structure of atoms
  - Discovery of the electron
  - Contributions of Lewis
Atomic structure and bonding
- Atomic structure
  - The Bohr model
  - The quantum mechanical model
    - The location of the electron
    - Quantum numbers
  - Shapes of atomic orbitals
  - The building-up principle
    - Hydrogen and helium
    - Lithium through neon
    - Sodium through argon
    - Potassium through krypton
- Periodic arrangement and trends
  - Arrangement of the elements
  - Periodic trends in properties
    - Atomic size
    - Ionization energy
    - Electron affinity
    - Electronegativity
Bonds between atoms
- The formation of ionic bonds
  - Lewis formulation of an ionic bond
  - The Born-Haber cycle
  - Factors favouring ionic bonding
- Covalent bonds
  - Lewis formulation of a covalent bond
  - Advanced aspects of Lewis structures
    - Multiple bonds
    - Resonance
    - Hypervalence
    - Incomplete-octet compounds
    - Electron-deficient compounds
- Molecular shapes and VSEPR theory
  - Applying VSEPR theory to simple molecules
  - Molecules with multiple bonds
  - Molecules with no central atom
  - Limitations of the VSEPR model
- The polarity of molecules
The quantum mechanics of bonding
- Valence bond theory
  - Formation of σ and π bonds
  - Promotion of electrons
  - Hybridization
  - Resonant structures
- Molecular orbital theory
  - Molecular orbitals of H₂ and He₂
  - Molecular orbitals of period-2 diatomic molecules
  - Molecular orbitals of polyatomic species
  - The role of delocalization
  - Comparison of the VB and MO theories
Intermolecular forces
- Repulsive force
- Dipole–dipole interaction
- Dipole–induced-dipole interaction
- Dispersion interaction
- The hydrogen bond
Varieties of solids
- Ionic solids
- Molecular solids
- Network solids
- Metals
Advanced aspects of chemical bonding
- Theories of bonding in complexes
  - Crystal field theory
  - Ligand field theory
- Compounds displaying unique bonding
  - Organometallic compounds
  - Boranes
  - Metal cluster compounds
- Computational approaches to molecular structure

References & Edit History Related Topics

Images & Videos

Understanding chemical reactions through combustion

Understanding John Dalton's atomic theory of matter

Investigate the magnetlike ionic bond formed when electrons transfer from one atom to another

For Students

bonding summary

Read Next

Molecular Machines: Making for the Future

Discover

Saint Lucia Day. Young girl wears Lucia crown (tinsel halo) with candles. Holds Saint Lucia Day currant laced saffron buns (lussekatter or Lucia's cats). Observed December 13 honor virgin martyr Santa Lucia (St. Lucy). Luciadagen, Christmas, Sweden

7 Winter Solstice Celebrations From Around the World

Orange basketball on black background and with low key lighting. Homepage 2010, arts and entertainment, history and society

The 10 Greatest Basketball Players of All Time

Coriander leaves, fresh green cilantro on wooden background, herbs

Why Does Cilantro Taste Like Soap to Some People?

Four year old boy with grandfather and father lighting Hanukkah menorah. Photo taken on: December 21st, 2009

Which Is Correct: Hanukkah or Chanukah?

Srinivasa Ramanujan, Indian mathematician and autodidact.

6 Interesting Facts about Srinivasa Ramanujan

Facsimile of one of William Henry Ireland's forgeries, a primitive self-portrait of William Shakespeare(tinted engraving). Published for Samuel Ireland, Norfolk Street, Strand, December 1, 1795. (W.H. Ireland, forgery)

The Time a Law Clerk Successfully Forged a New Shakespeare Play to Impress His Dad

A mug shot taken by the regional Colombia control agency in Medellin

Pablo Escobar: 8 Interesting Facts About the King of Cocaine

Lewis structures and the octet rule jointly offer a succinct indication of the type of bonding that occurs in molecules and show the pattern of single and multiple bonds between the atoms. There are many compounds, however, that do not conform to the octet rule. The most common exceptions to the octet rule are the so-called hypervalent compounds. These are species in which there are more atoms attached to a central atom than can be accommodated by an octet of electrons. An example is sulfur hexafluoride, SF₆, for which writing a Lewis structure with six S―F bonds requires that at ...(100 of 27318 words)

Access the full article

Help support true facts by becoming a member.