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Nitriles, RC≡N, are organic cyanides. They are named after the corresponding carboxylic acids by changing -ic acid to -onitrile, or -nitrile, whichever preserves a single letter o. Thus, CH3CN is acetonitrile (from acetic acid), whereas C6H5CN is benzonitrile (from benzoic acid). There are several methods of synthesizing nitriles. A common one is the treatment of an alkyl halide with sodium or potassium cyanide (RBr + KCN → RCN). Another method is the dehydration of the corresponding amide with a dehydrating agent such as phosphorus pentoxide (RCONH2→ RCN). An aldehyde can be used to prepare a nitrile by first being converted ...(100 of 9931 words)